Vibrational Spectra and Force Constants of Symmetric Tops,
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چکیده
The infrared spectrum of monoisotopic H3GeI has been investigated with a resolution of 0.04 cm -1 in the region of v6 and 2v6. Rotational analyses (o(J, K) ~ 7 • 10 cm ) of v6, 546.117(3), 2v^, 1094.731(4), and 2vg, 1091.530(4) cm", have been performed, and vibrational and rotational parameters of the apparently unperturbed v6 = 1 and 2 states have been obtained. Q branches of hot bands with v3 and v6 as lower states have been detected, and the anharmonicity constants .v36, .Y66 and g66 have been determined. The simultaneous analysis of vg', 2vJ and 2 v^ vjf provides an improved A0 value.
منابع مشابه
Vibrational Spectra and Force Constants of Symmetric Tops, XLVII. Rovibrational Spectra of Three Monoisotopic H3GeCl Species in the v6 Region
für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...
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تاریخ انتشار 2012